If you’ve begun to wear barefoot shoes only to start having pain, you might need to back off a little. You can find a barefoot shoe with more cushion, add an insole, and/or switch back and forth between your usual footwear and your new barefoot shoes. You can injure yourself if you rush it, so listen to the pain and respond to it. You will adapt faster if you do supplemental foot exercises to strengthen and condition your feet, but if problems persist consider consulting a professional (See How Do You Transition To Barefoot Shoes? for recommendations).
Further Reading:
Barefoot Shoes for Beginners
Foot Exercises for Transitioning to Barefoot Shoes
How To Find Shoes When You Have Bunions
A How To Find Shoes When You Have Bunions A bunion is when the metatarsal head (where the toe connects to the foot) moves away